Edwards Wilkinson: an interface with thermal fluctuations:
Consider domain wall
fluctuating at equilibrium at the temparature
. Here
is time,
defines the d-dimensional coordinate of the interface and
is the scalar height field. Hence, the domain wall separating two phases in a film has
, in a solid instead
.
Two assumptions are done:
- Overhangs, pinch-off are neglected, so that
is a scalar univalued function.
- The dynamics is overdamped, so that we can neglect the inertial term.
Derivation
The Langevin equation of motion is
The first term
is the elastic force trying to smooth the interface, the mobility
is inversily proportional to the viscosity. The second term is the Langevin Gaussian noise defined by the correlations
The symbol
indicates the average over the thermal noise.
The diffusion constant is fixed by the Eistein relation (fluctuation-dissipation theorem):
We set
The potential energy of surface tension can be expanded at the lowest order in the gradient:
Hence, we have the Edwards Wilkinson equation: